A real polynomial can have complex roots. Likewise, a real matrix can have complex eigenvalues and eigenvectors. For example, the matrix A=(2−112) represents a rotation in R2, followed by a stretch, so it doesn't have any real eigenvectors. (Ax is always tan−1(1/2) counterclockwise of x, so we can't have Ax=λx.) However, (2−112)(i1)=(−1+2i2+i)=(2+i)(i1).
As explained in the following video, we find complex eigenvalues and eigenvectors the same way that we find real eigenvalues and eigenvectors.
If A is a real matrix, then complex eigenvalues and eigenvectors come in conjugate pairs. If ξ=x+iy is an eigenvector with eigenvalue a+bi, then ˉξ=x−iy is an eigenvector with eigenvalue a−bi. In the plane spanned by y and x, A acts just like multiplication by (a−bba), namely rotation by tan−1(b/a) and stretching by √a2+b2.